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Entropic Separations of Mixtures of Aromatics by Selective Face‐to‐Face Molecular Stacking in One‐Dimensional Channels of Metal–Organic Frameworks and Zeolites |
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| Authors: | Ariana Torres‐Knoop Salvador R. G. Balestra Prof. Dr. Rajamani Krishna Prof. Dr. Sofía Calero Dr. David Dubbeldam |
| Affiliation: | 1. Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam (The Netherlands);2. Department of Physical, Chemical and Natural Systems, University Pablo de Olavide, Ctra. Utrera km. 1, 41013 Sevilla (Spain) |
| Abstract: | Separation of challenging mixtures using metal–organic frameworks can be achieved by an entropy‐driven mechanism, where one of the components can arrange into a “face‐to‐face” stacking, thus reducing its “footprint” and reaching a higher saturation loading. |
| Keywords: | aromatic compounds entropy mixtures MOFs separation |