Dual‐Doped Molybdenum Trioxide Nanowires: A Bifunctional Anode for Fiber‐Shaped Asymmetric Supercapacitors and Microbial Fuel Cells |
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Authors: | Minghao Yu Xinyu Cheng Yinxiang Zeng Zilong Wang Prof. Yexiang Tong Prof. Xihong Lu Prof. Shihe Yang |
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Affiliation: | 1. MOE of the Key Laboratory of Bioinorganic and Synthetic Chemistry, KLGHEI of Environment and Energy Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, P.R. China;2. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China |
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Abstract: | A novel in situ N and low‐valence‐state Mo dual doping strategy was employed to significantly improve the conductivity, active‐site accessibility, and electrochemical stability of MoO3, drastically boosting its electrochemical properties. Consequently, our optimized N‐MoO3?x nanowires exhibited exceptional performances as a bifunctional anode material for both fiber‐shaped asymmetric supercapacitors (ASCs) and microbial fuel cells (MFCs). The flexible fiber‐shaped ASC and MFC device based on the N‐MoO3?x anode could deliver an unprecedentedly high energy density of 2.29 mWh cm?3 and a remarkable power density of 0.76 μW cm?1, respectively. Such a bifunctional fiber‐shaped N‐MoO3?x electrode opens the way to integrate the electricity generation and storage for self‐powered sources. |
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Keywords: | energy conversion energy storage fuel cells molybdenum supercapacitors |
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