| Environmentally Benign Oxidation of Some Organic Sulfides with 34% Hydrogen Peroxide Catalyzed by Simple Heteropolyoxometalates |
| |
| 引用本文： | TAYEBEE Reza,ALIZADEH Mohammad Hassan. Environmentally Benign Oxidation of Some Organic Sulfides with 34% Hydrogen Peroxide Catalyzed by Simple Heteropolyoxometalates[J]. 中国化学, 2007, 25(9): 1340-1343. DOI: 10.1002/cjoc.200790249 |
| |
| 作者姓名： | TAYEBEE Reza ALIZADEH Mohammad Hassan |
| |
| 作者单位： | [1]Department of Chemistry, Sabzevar University, Sabzevar, 397, lran [2]Department of Chemistry, Ferdowsi University, Mashhad, 91779, lran |
| |
| 摘 要： | An environmentally benign oxygenation protocol was developed for selective oxidation of some types of aromatic and aliphatic sulfides in good to excellent yields utilizing 34% hydrogen peroxide catalyzed by simple heteropolyoxometalates in normal drinking water at room temperature. The catalysts could be recovered and reused for at least seven reaction cycles under the described reaction conditions without considerable loss of reactivity. This procedure introduced a new insight into the use of simple heteropolyanions as recoverable catalysts for the oxidation of organic sulfides by an environmentally acceptable protocol. Keywords
|
| 关 键 词： | 杂多酸 氧化作用 催化作用 硫化物 |
| 收稿时间： | 2006-11-24 |
| 修稿时间： | 2006-11-24 |
Environmentally Benign Oxidation of Some Organic Sulfides with 34% Hydrogen Peroxide Catalyzed by Simple Heteropolyoxometalates |
| |
| TAYEBEE,Reza,;ALIZADEH,Mohammad Hassan. Environmentally Benign Oxidation of Some Organic Sulfides with 34% Hydrogen Peroxide Catalyzed by Simple Heteropolyoxometalates[J]. Chinese Journal of Chemistry, 2007, 25(9): 1340-1343. DOI: 10.1002/cjoc.200790249 |
| |
| Authors: | TAYEBEE,Reza, ALIZADEH,Mohammad Hassan |
| |
| Affiliation: | [1]Department of Chemistry, Sabzevar University, Sabzevar, 397, lran; [2]Department of Chemistry, Ferdowsi University, Mashhad, 91779, lran |
| |
| Abstract: | An environmentally benign oxygenation protocol was developed for selective oxidation of some types of aromatic and aliphatic sulfides in good to excellent yields utilizing 34% hydrogen peroxide catalyzed by simple heteropolyoxometalates in normal drinking water at room temperature. The catalysts could be recovered and reused for at least seven reaction cycles under the described reaction conditions without considerable loss of reactivity. This procedure introduced a new insight into the use of simple heteropolyanions as recoverable catalysts for the oxidation of organic sulfides by an environmentally acceptable protocol. Keywords |
| |
| Keywords: | oxidation heteropolyacid catalysis hydrogen peroxide organic sulfide |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《中国化学》浏览原始摘要信息 |
|
点击此处可从《中国化学》下载全文 |
