Synthesis,Electronic Properties and WOLED Devices of Planar Phosphorus‐Containing Polycyclic Aromatic Hydrocarbons |
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| Authors: | Dr. François Riobé Rózsa Szűcs Dr. Pierre‐Antoine Bouit Dr. Denis Tondelier Bernard Geffroy Fátima Aparicio Julia Buendía Prof. Luis Sánchez Prof. Régis Réau Prof. László Nyulászi Prof. Muriel Hissler |
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| Affiliation: | 1. Institut des Sciences Chimiques de Rennes, UMR6226 CNRS‐Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex (France);2. Department of Inorganic Chemistry, Budapest University of Technology and Economics, 1521 Budapest (Hungary);3. Laboratoire de Physique des Interfaces et Couches Minces, CNRS UMR 7647, Ecole Polytechnique, 91128 Palaiseau (France);4. Laboratoire d'Innovation en Chimie des Surfaces et Nanosciences (LICSEN), UMR 3685 NIMBE, CEA Saclay 91191 Gif‐sur‐Yvette, Cedex (France);5. Departamento de Quimica Organica, Facultad de Ciencias Quimicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n 28040 Madrid (Spain) |
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| Abstract: | We describe the synthesis and the physical properties of polyaromatic hydrocarbons (PAHs) containing a phosphorus atom at the edge. In particular, the impact of the successive addition of aromatic rings on the electronic properties was investigated by experimental (UV/Vis absorption, fluorescence, cyclic voltammetry) and theoretical studies (DFT). The physical properties recorded in solution and in the solid state showed that the P‐containing PAHs exhibit properties expected for an emitter in white organic light‐emitting diodes (WOLEDs). |
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| Keywords: | aromaticity electronic structure energy conversion phosphorus heterocycles pi interactions |
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