| 一系列多核Mo(W)-Cu(Ag)-S簇合物的低热固相合成、成簇规律和机理的研究 |
| |
| 引用本文： | 郎建平,忻新泉. 一系列多核Mo(W)-Cu(Ag)-S簇合物的低热固相合成、成簇规律和机理的研究[J]. 化学学报, 1996, 54(5): 461-467 |
| |
| 作者姓名： | 郎建平 忻新泉 |
| |
| 作者单位： | 苏州大学化学系;南京大学化学系 |
| |
| 基金项目： | 江苏省教育委员会自然科学基金资助课题 |
| |
| 摘 要： | 本文报道了一系列多核Mo(W)-Cu(Ag)-S族合物的低热固相合成, 发现硫代钼(钨)酸铵与铜(银)的成簇规律主要与固相反应温度密切相关, 提出了四核至七核Mo(W)-Cu(Ag)-S簇合物的可能成簇机理。
|
| 关 键 词： | 红外分光光度法 铜络合物 钼络合物 簇状化合物 硫络合物 四园衍射仪 江苏省教育委员会自然科学基金 |
Studies on solid state synthesis, regularity and mechanism of cluster formation of a series of Mo(W)-Cu(Ag)-S cluster compounds at low heating temperatures |
| |
| LANG JIANPING,XIN XINQUAN. Studies on solid state synthesis, regularity and mechanism of cluster formation of a series of Mo(W)-Cu(Ag)-S cluster compounds at low heating temperatures[J]. Acta Chimica Sinica, 1996, 54(5): 461-467 |
| |
| Authors: | LANG JIANPING XIN XINQUAN |
| |
| Abstract: | In this paper, solid state synthesis of a series of Mo(W)-Cu(Ag)-S cluster compounds at low heating temperatures has been reported. It has been found that the regularity of cluster formation of thiomolybdate (or thiotungstate) with copper (or silver) is closely relevant to the solid state reaction temperatures. The possible mechanism of cluster formation of Mo(W)-Cu(Ag)-S cluster compounds with nuclearity from four to seven has been suggested. |
| |
| Keywords: | INFRARED SPECTROPHOTOMETRY COPPER COMPLEX MOLYBDENUM COMPLEX CLUSTER COMPOUND SULFIDE COMPLEX FOUR-CIRCLE DIFFRACTOMETER |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《化学学报》浏览原始摘要信息 |
|
点击此处可从《化学学报》下载全文 |
