A Dinitrogen Dicopper(I) Complex via a Mixed‐Valence Dicopper Hydride |
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| Authors: | Shiyu Zhang Hengameh Fallah Evan J. Gardner Dr. Subrata Kundu Dr. Jeffery A. Bertke Prof. Thomas R. Cundari Prof. Timothy H. Warren |
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| Affiliation: | 1. Department of Chemistry, Georgetown University, Washington, DC, USA;2. Department of Chemistry, Center for Advanced Scientific Computing and Modeling (CASCaM), University of North Texas, Denton, TX, USA |
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| Abstract: | Low‐temperature reaction of the tris(pyrazolyl)borate copper(II) hydroxide [iPr2TpCu]2(μ‐OH)2 with triphenylsilane under a dinitrogen atmosphere gives the bridging dinitrogen complex [iPr2TpCu]2(μ‐1,2‐N2) ( 3 ). X‐ray crystallography reveals an only slightly activated N2 ligand (N‐N: 1.111(6) Å) that bridges between two monovalent iPr2TpCu fragments. While DFT studies of mono‐ and dinuclear copper dinitrogen complexes suggest weak π‐backbonding between the d10 CuI centers and the N2 ligand, they reveal a degree of cooperativity in the dinuclear Cu‐N2‐Cu interaction. Addition of MeCN, CNAr2,6‐Me, or O2 to 3 releases N2 with formation of iPr2TpCu(L) (L=NCMe, CNAr2,6‐Me2) or [iPr2TpCu]2(μ‐η2:η2‐O2) ( 1 ). Addition of triphenylsilane to [iPr2TpCu]2(μ‐OH)2 in pentane allows isolation of a key intermediate [iPr2TpCu]2(μ‐H) ( 5 ). Although 5 thermally decays under N2 to give 3 , it reduces unsaturated substrates, such as CO and HC≡CPh to HC(O)H and H2C=CHPh, respectively. |
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| Keywords: | copper dinitrogen hydride mixed-valent compounds reduction |
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