Solvent‐Driven Chiral‐Interaction Reversion for Organogel Formation |
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| Authors: | Wenrui Chen Ziyu Lv Peng Xiong Prof. Dr. Taolei Sun |
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| Affiliation: | State Key Laboratory of Advanced Technology for Materials, Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070 (P.R. China) |
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| Abstract: | For chiral gels and related applications, one of the critical issues is how to modulate the stereoselective interaction between the gel and the chiral guest precisely, as well as how to translate this information into the macroscopic properties of materials. Herein, we report that this process can also be modulated by nonchiral solvents, which can induce a chiral‐interaction reversion for organogel formation. This process could be observed through the clear difference in gelation speed and the morphology of the resulting self‐assembly. This chiral effect was successfully applied in the selective separation of quinine enantiomers and imparts “smart” merits to the gel materials. |
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| Keywords: | chiral gels chiral recognition host– guest systems self‐assembly solvent effects |
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