| 雌酮和雌二醇类似物的质谱研究 |
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| 引用本文： | 袁希召. 雌酮和雌二醇类似物的质谱研究[J]. 化学学报, 1983, 41(1): 79-85 |
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| 作者姓名： | 袁希召 |
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| 作者单位： | 兰州化学工业公司化工研究院 |
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| 摘 要： | 本文报道九种雌酮和雌二醇类似物的质谱,并解释了碎片离子的生成途径。讨论了取代基对裂解方式的影响。这种裂解规律的研究有助于这类新化合物的质谱鉴定.
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| 关 键 词： | 质谱法 雌甾二醇 雌甾酮 |
A mass spectrometric study on the analogues of estrone and estradiol |
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| YUAN XIZHAO. A mass spectrometric study on the analogues of estrone and estradiol[J]. Acta Chimica Sinica, 1983, 41(1): 79-85 |
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| Authors: | YUAN XIZHAO |
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| Abstract: | The mass spectra of nine analogues of estrone and estradiol have been analyzed, in which three more principal fragmentation ions, g, h, j other than those which correspond to the ions suggested by Djerassi et al. have been interpreted. One of them, j is a new fragment ion resulted from the skeletal fragmentation in the presence of 17α-ethynyl group (6, 7, 8). |
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| Keywords: | MASS SPECTROGRAPHY ESTRADIOL ESTRONE |
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