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可充锂电池醌类化合物电极材料
引用本文:DAWUT Gulbahar,卢勇,赵庆,梁静,陶占良,陈军. 可充锂电池醌类化合物电极材料[J]. 物理化学学报, 2016, 32(7): 1593-1603. DOI: 10.3866/PKU.WHXB201605231
作者姓名:DAWUT Gulbahar  卢勇  赵庆  梁静  陶占良  陈军
作者单位:1 南开大学化学学院,先进能源材料化学教育部重点实验室,天津3000712 喀什大学化学与环境科学学院,新疆特色药食用植物资源化学重点实验室,新疆喀什844000
基金项目:the National Natural Science Foundation of China(51231003);Ministry of Education, China(B12015);Ministry of Education, China(IRT13R30);Natural Science Foundation of Xinjiang Uygur Autonomous Region, China(201318101-15)
摘    要:醌类化合物电极材料具有理论比容量高、结构可设计、成本低廉和绿色可持续等优点,被认为是可充锂电池理想的电极材料。本文介绍了醌类化合物电极材料的分类及其结构特点、电化学工作原理及其电化学性能,对醌类化合物的发展、面临的问题等方面进行了概括,探讨了提高该类电极材料电化学性能的方法,并对醌类化合物电极材料的发展方向进行了展望。

关 键 词:可充锂电池  有机电极材料  醌类化合物  理论比容量  电化学性能  
收稿时间:2016-03-31

Quinones as Electrode Materials for Rechargeable Lithium Batteries
Yong LU,Qing ZHAO,Jing LIANG,Zhan-Liang TAO,Jun CHEN. Quinones as Electrode Materials for Rechargeable Lithium Batteries[J]. Acta Physico-Chimica Sinica, 2016, 32(7): 1593-1603. DOI: 10.3866/PKU.WHXB201605231
Authors:Yong LU  Qing ZHAO  Jing LIANG  Zhan-Liang TAO  Jun CHEN
Affiliation:1. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, P. R. China;2. College of Chemistry and Environmental Science, Key Laboratory of Xinjiang Native Medicinal and Edible Plant Resources Chemistry, Kashgar University, Kashgar 844000, Xinjiang Uygur Autonomous, P. R. China
Abstract:Owing to advantages such as high theoretical specific capacity, designable structure, low cost and environmental friendliness, organic quinone compounds have been proposed as promising electrode materials for rechargeable lithium batteries. In this review, we first introduce the classification, structural characteristics, electrochemical reaction mechanism and performance of quinone-based electrodes. We then summarize the recent progress, existing problems and strategies for improving the electrochemical performance of quinonebased compounds and polymers. Finally, we also discuss the future development of such materials for use in lithium batteries.
Keywords:Rechargeable lithium battery  Organic electrode material  Quinone  Theoretical specific capacity  Electrochemical performance  
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