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Incommensurate-commensurate magnetic phase transition in double tungstate Li2Co(WO4)2
Abstract:Magnetic susceptibility, specific heat, and neutron powder diffraction measurements have been performed on polycrystalline Li$_{2}$Co(WO$_{4}$)$_{2}$ samples. Under zero magnetic field, two successive magnetic transitions at $T_{rm N1}sim 9.4$ K and $T_{rm N2}sim 7.4$ K are observed. The magnetic ordering temperatures gradually decrease as the magnetic field increases. Neutron diffraction reveals that Li$_{2}$Co(WO$_{4}$)$_{2}$ enters an incommensurate magnetic state with a temperature dependent $bm k$ between $T_{rm N1}$ and $T_{rm N2}$. The magnetic propagation vector locks-in to a commensurate value $bm k = (1/2, 1/4, 1/4)$ below $T_{rm N2}$. The antiferromagnetic structure is refined at 1.7 K with Co$^{2+}$ magnetic moment 2.8(1) $mu_{rm B}$, consistent with our first-principles calculations.
Keywords:Li2Co(WO4)2  incommensurate-commensurate magnetic transition  
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