Active palladium catalyst supported by bulky diimine ligand catalyzed Suzuki–Miyaura coupling reaction in water under phosphane‐free and low catalyst loading conditions |
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| Authors: | Mohammad Gholinejad Vahid Karimkhani Il Kim |
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| Affiliation: | 1. Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan, Iran;2. Department of Polymer Engineering and Color Technology, Amirkabir University of Technology, Tehran, Iran;3. WCU Center for Synthetic Polymer Bioconjugate Hybrid Materials, Department of Polymer Science and Engineering, Pusan National University, Pusan, Korea |
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| Abstract: | A new catalytic system based on palladium and bulky diimine ligand for Suzuki–Miyaura coupling reaction of aryl iodides, bromides and chlorides in neat water is described. The desired biphenyl products were obtained in high to excellent yields for aryl iodides and bromides in the presence of low catalyst loading. Air‐stable catalyst has been recycled for the reaction of iodobenzene with phenylboronic acid for five consecutive runs. Copyright © 2014 John Wiley & Sons, Ltd. |
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| Keywords: | Suzuki palladium bulky diimine supported water |
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