Mechanistic Insights into the Fluorescence Quenching of Rhodamine 6G by Graphene Oxide |
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| Authors: | Lu Chen Lei Zhang Shen-long Jiang Qun Zhang |
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| Affiliation: | Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at the Microscale, Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei 230026, China |
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| Abstract: | The fluorescence quenching of Rhodamine 6G (R6G) by graphene oxide (GO) was interrogated by R6G fluorescence measurements using a set of controlled GO samples with varied C/O ratios as the quencher.The carbonyl groups on the GO nanosheet turned to play a dominant role in quenching the R6G fluorescence.The quenching in the static regime can be described by the "sphere of action" model.The significant absorption of the R6G fluorescence by the ground-state complex formed between R6G and GO was identified to be responsible for the static quenching.This work offers helpful insights into the fluorescence quenching mechanisms in the R6G/GO system. |
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| Keywords: | Graphene oxide Rhodamine 6G Fluorescence Carbonyl group Static quenching Sphere of action Ground-state complex |
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