Transition‐metal‐catalyzed Chelation‐assisted C–H Functionalization of Aromatic Substrates |
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| Authors: | Binlin Zhao Zhuangzhi Shi Yu Yuan |
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| Affiliation: | 1. College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China;2. State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China |
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| Abstract: | In the past decade, transition‐metal‐catalyzed C–H activations have been very popular in the research field of organometallic chemistry, and have been considered as efficient and convenient strategies to afford complex natural products, functional advanced materials, fluorescent compounds, and pharmaceutical compounds. In this account, we begin with a brief introduction to the development of transition‐metal‐catalyzed C–H activation, especially the development of transition‐metal‐catalyzed chelation‐assisted C–H activation. Then, a more detailed discussion is directed towards our recent studies on the transition‐metal‐catalyzed chelation‐assisted oxidative C–H/C–H functionalization of aromatic substrates bearing directing functional groups. |
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| Keywords: | C– H functionalization copper palladium rhodium transition metals |
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