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Studies on Effect of Tri(2-hydroxypropyl), Tri(2-hydroxybutyl) and Tri(hydroxythiodiethylene) Borates on Thermal and Heat Properties of Rigid Polyurethane-Polyisocyanurate Foams
引用本文:CZUPRYNSKI Boguslaw PACIOREK-SADOWSKA Joanna LISZKOWSKA Joanna. Studies on Effect of Tri(2-hydroxypropyl), Tri(2-hydroxybutyl) and Tri(hydroxythiodiethylene) Borates on Thermal and Heat Properties of Rigid Polyurethane-Polyisocyanurate Foams[J]. 中国化学, 2006, 24(12): 1796-1799. DOI: 10.1002/cjoc.200690336
作者姓名:CZUPRYNSKI Boguslaw PACIOREK-SADOWSKA Joanna LISZKOWSKA Joanna
作者单位:Casimir the Great Academy of Bydgoszcz, Chodkiewicza str. 30, 85-064 Bydgoszcz, Poland
摘    要:Effect of tri(2-hydroxypropyl), tri(2-hydroxybutyl)and tri(hydroxythiodiethylene) borates (BT2HB, BT2HP and BTHET) on the thermal and heat properties of the rigid polyurethane-polyisocyanurate (PUR-PIR) foams was investigated: Increasing amounts of BT2HB and BT2HP in the foam composition, from 0.05 to 0.4 of chemical equivalent, caused increases in the softening point, the temperature of the first mass loss, the extrapolated tempera- ture of the main mass loss foam and temperature of the highest rate of the mass loss. In the case when BTHTE was added to the foam compositions, the lower increase in the mentioned above characteristic temperatures was observed as compared to those of standard foam (without borate added).

关 键 词:热阻 热解重量分析 软化点 三(2-羟基丙基)三(2-羟基丁基) 三(羟基硫二乙烯)硼酸酯 聚亚安酯 聚异氰尿酸酯
收稿时间:2005-09-27
修稿时间:2005-09-272006-08-04

Studies on Effect of Tri(2-hydroxypropyl),Tri(2-hydroxybutyl)and Tri(hydroxythiodiethylene) Borates on Thermal and Heat Properties of Rigid Polyurethane-Polyisocyanurate Foams
CZUPRYNSKI Boguslaw, PACIOREK-SADOWSKA Joanna, LISZKOWSKA Joanna. Studies on Effect of Tri(2-hydroxypropyl),Tri(2-hydroxybutyl)and Tri(hydroxythiodiethylene) Borates on Thermal and Heat Properties of Rigid Polyurethane-Polyisocyanurate Foams[J]. Chinese Journal of Chemistry, 2006, 24(12): 1796-1799. DOI: 10.1002/cjoc.200690336
Authors:CZUPRYNSKI Boguslaw   PACIOREK-SADOWSKA Joanna   LISZKOWSKA Joanna
Affiliation:Casimir the Great Academy of Bydgoszcz, Chodkiewicza str. 30, 85-064 Bydgoszcz, Poland
Abstract:Effect of tri(2-hydroxypropyl),tri(2-hydroxybutyl) and tri(hydroxythiodiethylene) borates (BT2HB,BT2HP and BTHET) on the thermal and heat properties of the rigid polyurethane-polyisocyanurate (PUR-PIR) foams was in- vestigated.Increasing amounts of BT2HB and BT2HP in the foam composition,from 0.05 to 0.4 of chemical equivalent,caused increases in the softening point,the temperature of the first mass loss,the extrapolated tempera- ture of the main mass loss foam and temperature of the highest rate of the mass loss.In the case when BTHTE was added to the foam compositions,the lower increase in the mentioned above characteristic temperatures was ob- served as compared to those of standard foam (without borate added).
Keywords:rigid PUR-PIR foam   heat and thermal resistance   thermogravimetric analysis   softening point
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