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Micro‐photoluminescence spectroscopy on heavily‐doped layers of silicon solar cells
Authors:Hieu T. Nguyen  Di Yan  Fan Wang  Peiting Zheng  Young Han  Daniel Macdonald
Affiliation:1. Research School of Engineering, College of Engineering and Computer Science, The Australian National University, Canberra, Australia;2. Department of Electronic Materials Engineering, Research School of Physics and Engineering, The Australian National University, Canberra, Australia
Abstract:We report and explain the photoluminescence spectra emitted from silicon solar cells with heavily‐doped layers at the surface. A micro‐photoluminescence spectroscopy system is employed to investigate the total spectrum emitted from both the heavily‐doped layer and the silicon substrate with micron‐scale spatial resolution. The two regions of the device give rise to separate photoluminescence peaks, due to band‐gap narrowing effects in the highly‐doped layer. Two key parameters, the absorption depth of the excitation wavelength, and the sample temperature, are shown to be critical to reveal the separate signatures from the two regions. Finally, this technique is applied to locally diffused and laser‐doped regions on silicon solar cell pre‐cursors, demonstrating the potential value of this micron‐scale technique in studying and optimizing locally doped regions. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)
Keywords:band gaps  crystals  silicon  doping  photoluminescence  solar cells
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