Intramolecular Singlet Fission in Oligoacene Heterodimers |
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| Authors: | Samuel N. Sanders Dr. Elango Kumarasamy Andrew B. Pun Dr. Michael L. Steigerwald Dr. Matthew Y. Sfeir Prof. Luis M. Campos |
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| Affiliation: | 1. Department of Chemistry, Columbia University, New York, NY, USA;2. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, USA |
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| Abstract: | We investigate singlet fission (SF) in heterodimers comprising a pentacene unit covalently bonded to another acene as we systematically vary the singlet and triplet pair energies. We find that these energies control the SF process, where dimers undergo SF provided that the resulting triplet pair energy is similar or lower in energy than the singlet state. In these systems the singlet energy is determined by the lower‐energy chromophore, and the rate of SF is found to be relatively independent of the driving force. However, triplet pair recombination in these heterodimers follows the energy gap law. The ability to tune the energies of these materials provides a key strategy to study and design new SF materials—an important process for third‐generation photovoltaics. |
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| Keywords: | conjugated materials heterodimers organic electronics photophysics singlet fission |
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