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Palladium(IV) in an Oxoanionic Environment: The XeF2 Assisted Synthesis of [Pd(S2O7)3]2− |
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| Authors: | Dr. Jörn Bruns M. Sc. David van Gerven Prof. Dr. Thorsten Klüner Prof. Dr. Mathias S. Wickleder |
| Affiliation: | 1. Universit?t Innsbruck, Institut für Allgemeine, Anorganische und Theoretische Chemie, Innsbruck, Austria;2. Justus Liebig Universit?t Giessen, Institut für Anorganische und Analytische Chemie, Giessen, Germany;3. Carl von Ossietzky Universit?t Oldenburg, Institut für Chemie, Oldenburg, Germany |
| Abstract: | For the first time tetravalent palladium is detected, coordinated exclusively by simple oxoanions. Stabilization was achieved by formation of the [Pd(S2O7)3]2? complex in which three chelating disulfate groups surround the metal atom. The salt K2[Pd(S2O7)3] could only be obtained if the reaction of K2[PdCl6] and neat SO3 was performed in the presence of XeF2. |
| Keywords: | density functional theory disulfate palladium structure elucidation vibrational spectroscopy |