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超疏水滤纸的制备与应用
引用本文:周聪,陈硕,朱卫桃,袁平,杨子辉,李彬,陈波. 超疏水滤纸的制备与应用[J]. 应用化学, 2012, 29(3): 297-303. DOI: 10.3724/SP.J.1095.2012.00175
作者姓名:周聪  陈硕  朱卫桃  袁平  杨子辉  李彬  陈波
作者单位:(1.湖南师范大学“化学生物学及中药分析”教育部重点实验室 长沙 410081;2.湖南大学材料科学与工程学院 长沙)
基金项目:国家自然科学基金(20927005);湖南省研究生创新课题(CX2010B221)资助项目
摘    要:对SiO2纳米粒子进行硅烷化改性,再将其修饰到滤纸上,制备出静态水接触角>150°的超疏水滤纸,对制备条件进行了优化。 用热重分析及扫描电子显微镜对超疏水滤纸表征后发现,二氧化硅纳米粒子在滤纸纤维表面形成一层包裹层,即纳米级粗糙结构,这种结构对滤纸的疏水性具有关键作用。 对滤纸的油水分离性能进行了研究,发现其对非均相体系和高粘度油水混合物具有很好的分离效果。

关 键 词:超疏水滤纸  纳米粒子  硅烷化改性  油水分离  
收稿时间:2011-04-27
修稿时间:2011-07-05

Preparation and Application of Super-hydrophobic Filter Paper
ZHOU Cong , CHEN Shuo , ZHU Weitao , YUAN Ping , YANG Zihui , LI Bin , CHEN Bo. Preparation and Application of Super-hydrophobic Filter Paper[J]. Chinese Journal of Applied Chemistry, 2012, 29(3): 297-303. DOI: 10.3724/SP.J.1095.2012.00175
Authors:ZHOU Cong    CHEN Shuo    ZHU Weitao    YUAN Ping    YANG Zihui    LI Bin    CHEN Bo
Affiliation:(1.Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research,Ministry of Education,Hunan Normal University,Changsha 410081;2.College of Materials & Engineering of Hunan University,Changsha)
Abstract:Super-hydrophobic filter papers were prepared by using SiO2 nano-particles midified by silylating reagent.The water contact angle on the filter papers was higher than 150°.Thermogravimetry and scanning electron microscope were used to characterize the filter paper.The results showed that SiO2 nano-particle layer was formed on the micro-fibers of filter paper.The combined nano-and micro-structure produced the super-hydrophobic property of the filter paper.The oil-water separation ability of the paper was also investigated,high oil-water separation efficiencies of the paper,especially for high-viscosity mixtures,were confirmed.
Keywords:super-hydrophobic filter paper  nanoparticles  silylation modification  oil-water separation
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