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| N-苯基硫代膦酰基氨基酸及氨基乙酸乙酯衍生物的研究 | |
| 引用本文： | 陈茹玉,方建兴. N-苯基硫代膦酰基氨基酸及氨基乙酸乙酯衍生物的研究[J]. 高等学校化学学报, 1985, 6(7): 603 |
| 作者姓名： | 陈茹玉 方建兴 |
| 作者单位： | 南开大学元素有机化学研究所 |
| 摘 要： | 本文报告了42个新的N-苯基硫代膦酰基氨基酸及氨基乙酸乙酯衍生物的制备;改进了N-膦酰基氨基酸酯衍生物的制备方法;对衍生物的生物活性以及某些衍生物在酸碱水溶液中的稳定性进行了初步探讨。 |
| 收稿时间： | 1984-04-07 |
Study on the Derivatives of N-Phenylphosphonothioylamino Acids and N-Phenylphosphonothioylglycine Ethyl Esters |
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| Chen Ruyu,Fang Iianxing. Study on the Derivatives of N-Phenylphosphonothioylamino Acids and N-Phenylphosphonothioylglycine Ethyl Esters[J]. Chemical Research In Chinese Universities, 1985, 6(7): 603 | |
| Authors: | Chen Ruyu Fang Iianxing |
| Affiliation: | Institute of Elemento-Organie Chemistry, Nankai University, Tianjin |
| Abstract: | Forty-two new organic phosphorus compounds have been prepared. In the synthesis of derivatives Ⅱ and Ⅲ, a simplified procedure has been used by the modification of the methods reported in literature. The by-product with the formulas phP(S)(NHCH2COOC2H5)2 and phP(S)(OR)2(R = ο-NO2C6H4, 2-NO2-4,5-(CH3)2C6H2, 2,4,5-Cl3C6H2) have been isolated from the react mixture of some of derivatives Ⅱ. The preliminary tests for the biological activities of derivatives Ⅰ, Ⅱ and Ⅲ and the stability of derivatives Ⅱ in alkaline and acidic solutions have been carried out. |
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