| 聚苯乙烯负载多吡啶铂(Ⅱ)炔基络合物的合成 |
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| 引用本文： | 彭明丽,吴骊珠,张丽萍,佟振合. 聚苯乙烯负载多吡啶铂(Ⅱ)炔基络合物的合成[J]. 影像科学与光化学, 2004, 22(5): 321-326. DOI: 10.7517/j.issn.1674-0475.2004.05.321 |
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| 作者姓名： | 彭明丽 吴骊珠 张丽萍 佟振合 |
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| 作者单位： | 中国科学院理化技术研究所, 北京, 100101 |
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| 摘 要： | 通过自由基共聚成功地将具有高磷光发光效率的-苯基-2,2’-二联吡啶(C^N^N)Pt(Ⅱ)苯乙炔络合物共价键合在聚苯乙烯高分子骨架上,得到了发射磷光的聚合物.实验表明,发光聚合物基本保持了多吡啶铂络合物单体的光谱性质.具有与小分子相当的光致发光效率.
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| 关 键 词： | 6-苯基2 2’-二联吡啶(C^N^N)Pt(Ⅱ)苯乙炔 聚苯乙烯 发光聚合物 |
| 收稿时间： | 2004-06-14 |
Synthesis of Polystyrene-Supported Polypyridyl Platinum Acetylide Complex |
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| PENG Ming-li,WU Li-zhu,ZHANG Li-ping,TONG Zhen-he. Synthesis of Polystyrene-Supported Polypyridyl Platinum Acetylide Complex[J]. Imaging Science and Photochemistry, 2004, 22(5): 321-326. DOI: 10.7517/j.issn.1674-0475.2004.05.321 |
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| Authors: | PENG Ming-li WU Li-zhu ZHANG Li-ping TONG Zhen-he |
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| Affiliation: | Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, P. R. China |
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| Abstract: | 6-phenyl-2,2'-bipyridyl platinum (Ⅱ) acetylide complex with high luminescent quantum yield was covalently bonded to polystyrene by radical copolymerization.It was noted that the lumeniscent polymer displayed the similar spectroscopic properties compared with those of 6-phenyl-2,2'-bipyridyl platinum (Ⅱ) acetylide complex. |
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| Keywords: | 6-phenyl-2,2'-bipyridyl platinum (Ⅱ) acetylide complex polystyrene luminescent polymer |
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