| 三价银配合物氧化1,4-丁二胺的反应动力学及机理研究 |
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| 引用本文： | SONG Changying,SHAN Jinhuan,Shen Shigang,Sun Hanwen. 三价银配合物氧化1,4-丁二胺的反应动力学及机理研究[J]. 中国化学, 2009, 27(3): 452-454. DOI: 10.1002/cjoc.200990074 |
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| 作者姓名： | SONG Changying SHAN Jinhuan Shen Shigang Sun Hanwen |
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| 作者单位： | College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China |
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| 摘 要： | 碱性介质中, 在离子强度不变的条件下, 用广度法研究了三价银配合物氧化1,4-丁二胺的动力学及机理. 反应对三价银配合物和都是一级反应, 二级反应速率常数(k’) 随碱浓度的增大而增大,随糕碘酸根离子浓度的增大而减小. 据此提出了适合此反应的反应机理, 并计算得到了反应的热力学参数.
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| 关 键 词： | 三价银配合物 1 4-丁二胺 反应动力学及机理 氧化还原反应 |
| 收稿时间： | 2008-05-18 |
| 修稿时间： | 2008-08-22 |
A Kinetically Mechanistic Investigation of Oxidation of 1,4‐Butanediamine by Ag(III) Complex in Alkaline Medium |
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| Changying SONG,Jinhuan SHAN,Shigang Shen,Hanwen Sun. A Kinetically Mechanistic Investigation of Oxidation of 1,4‐Butanediamine by Ag(III) Complex in Alkaline Medium[J]. Chinese Journal of Chemistry, 2009, 27(3): 452-454. DOI: 10.1002/cjoc.200990074 |
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| Authors: | Changying SONG Jinhuan SHAN Shigang Shen Hanwen Sun |
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| Affiliation: | 1. Tel.: 0086‐0312‐5079359;2. Fax: 0086‐0312‐5079525;3. College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China |
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| Abstract: | Kinetics and mechanism of oxidation of 1,4‐butanediamine by a Ag(III) complex were studied spectrophotometrically in alkaline medium at constant ion strength. The reaction shows first order with respect to the Ag(III) complex and 1,4‐butanediamine respectively. The second order rate constant, k′, increased with the increasing in [OH?], and decreased with the increasing in [IO4?]. A plausible mechanism was proposed from the kinetics study. The rate equations derived from the mechanism can explain all experimental phenomena. The activation parameters were calculated. |
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| Keywords: | Ag(III) complex 1,4‐butanediamine kinetics and mechanism redox reaction |
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