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Synthesis of Trifluoromethylthiolated Alkenes and Ketones by Decarboxylative Functionalization of Cinnamic Acids
Authors:Shen Pan  Dr. Yangen Huang  Dr. Feng‐Ling Qing
Affiliation:1. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, China;2. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai, China
Abstract:A tunable decarboxylative trifluoromethylthiolation of cinnamic acids with AgSCF3 was developed to afford trifluoromethylthiolated alkenes or ketones by using transition metal‐mediated conditions.
Keywords:alkene  cinnamic acid  decarboxylation  ketone  trifluormethylthiolation
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