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A Molecular Ferroelectric Thin Film of Imidazolium Perchlorate That Shows Superior Electromechanical Coupling
Authors:Dr. Yi Zhang  Prof. Yuanming Liu  Dr. Heng‐Yun Ye  Dr. Da‐Wei Fu  Wenxiu Gao  He Ma  Prof. Zhiguo Liu  Prof. Yunya Liu  Prof. Wen Zhang  Prof. Jiangyu Li  Prof. Guo‐Liang Yuan  Prof. Ren‐Gen Xiong
Affiliation:1. Ordered Matter Science Research Center, Southeast University, Nanjing 211189 (P. R. China);2. Department of Mechanical Engineering, University of Washington, Seattle, WA 98195 (USA);3. School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094 (P.R. China);4. Department of Materials Science and Engineering, Nanjing University, Nanjing 210093 (P.R. China);5. Faculty of Materials, Optoelectronics and Physics, Key Laboratory of Low Dimensional Materials and Application Technology of Ministry of Education, Xiangtan University, Hunan 411105 (China)
Abstract:Molecular ferroelectric thin films are highly desirable for their easy and environmentally friendly processing, light weight, and mechanical flexibility. A thin film of imidazolium perchlorate processed from aqueous solution is an excellent molecular ferroelectric with high spontaneous polarization, high Curie temperature, low coercivity, and superior electromechanical coupling. These attributes make it a molecular alternative to perovskite ferroelectric films in sensing, actuation, data storage, electro‐optics, and molecular/flexible electronics.
Keywords:domains  imidazolium perchlorate  molecular ferroelectrics  piezoelectric force microscopy  thin films
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