| 氟烷基取代的双酚A类衍生物的合成 |
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| 引用本文： | 唐婷,杨雪艳,陈曦,吴范宏. 氟烷基取代的双酚A类衍生物的合成[J]. 高等学校化学学报, 2010, 31(6): 1179-1183 |
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| 作者姓名： | 唐婷 杨雪艳 陈曦 吴范宏 |
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| 作者单位： | 杭州师范大学医药卫生管理学院,杭州,310036;华东理工大学化学与分子工程学院,上海,200237;华东理工大学化学与分子工程学院,上海,200237;中国科学院上海有机化学研究所有机氟化学重点实验室,上海,200032 |
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| 摘 要： | 利用相转移催化剂十六烷基三甲基溴化铵(CTMAB)催化的连二亚硫酸钠引发的苯酚衍生物与含氟碘代烷的氟烷基化反应, 合成了含氟烷基取代的酚类化合物. 研究了双酚A与含氟碘代烷的氟烷基化反应, 得到了一类重要的含氟单体, 即含氟烷基取代的双酚A衍生物. 通过改变含氟碘代烷与双酚A的摩尔比, 可以得到单取代、二取代和四取代的含氟烷基双酚A衍生物.
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| 关 键 词： | 氟烷基化 双酚A 苯酚衍生物 |
| 收稿时间： | 2009-06-23 |
Synthesis of Fluoroalkyl Substituted Biphenol A Derivatives |
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| TANG Ting,YANG Xue-Yan,CHEN Xi,WU Fan-Hong. Synthesis of Fluoroalkyl Substituted Biphenol A Derivatives[J]. Chemical Research In Chinese Universities, 2010, 31(6): 1179-1183 |
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| Authors: | TANG Ting YANG Xue-Yan CHEN Xi WU Fan-Hong |
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| Affiliation: | 1. Pharmaceutical Sciences Department, Medicine and Health Manage College, Hangzhou Normal University, Hangzhou 310036, China;2. School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China;3. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | Synthesis of new biphenol A derivatives are significant due to their utility as monomers.In this paper,the fluoroalkylation of phenol derivatives initiated by sodium dithionite in the presence of CTMAB as phase catalyst was investigated to give fluoralkyl phenols.When biphenol A was used as the substrate,some new biphenol A derivatives was obtained.Mono-,di-or tetra-fluoroalky subtstitued biphenol A derivatives,which may be important monomers,were prepared when different molar ratio of fluoroalkyl iodides a... |
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| Keywords: | Fluoroalkylation Biphenol A Phenol derivative |
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