| 间二甲苯氨氧化m—509催化剂失活研究 |
| |
| 引用本文： | 黄驰,郑穹,谢光勇,陈远荫,李国珍,肖修云.间二甲苯氨氧化m—509催化剂失活研究[J].武汉大学学报(理学版),2001,47(4):438-440. |
| |
| 作者姓名： | 黄驰 郑穹 谢光勇 陈远荫 李国珍 肖修云 |
| |
| 作者单位： | 1. 武汉大学化学与分子科学学院,
2. 湖南南天实业股份有限公司, |
| |
| 摘 要： | 对间二甲苯氨氧化制备间苯二腈新型m－509催化剂，及其在工业流化床反应器上进行试验后的下床催化剂，进行了宏观物理性质、X光电子能谱、等离子发射光谱等表征分析，发现催化剂在工业安装上使用6个月后，其表面存在大量积炭，催化剂活性组分流失较严重，活性组分流失是催化剂活性下的主要原因，而积炭对催化剂的活性影响不大。
|
| 关 键 词： | 催化剂失活 催化剂表征 氨氧化 间苯二腈 间二甲苯氨 催化剂活性 |
| 文章编号： | 0253-9888(2001)04-0438-03 |
| 修稿时间： | 2000年6月25日 |
Research on Deactivation of m-509 Ammoxidation Catalyst of m-Xylene |
| |
| HUANG Chi ,ZHENG Qiong ,XIE Guang-yong ,CHEN Yuan-yin ,LI Guo-zhen ,XIAO Xiu-yun.Research on Deactivation of m-509 Ammoxidation Catalyst of m-Xylene[J].JOurnal of Wuhan University:Natural Science Edition,2001,47(4):438-440. |
| |
| Authors: | HUANG Chi ZHENG Qiong XIE Guang-yong CHEN Yuan-yin LI Guo-zhen XIAO Xiu-yun |
| |
| Institution: | HUANG Chi 1,ZHENG Qiong 1,XIE Guang-yong 1,CHEN Yuan-yin 1,LI Guo-zhen 2,XIAO Xiu-yun 2 |
| |
| Abstract: | The new ammoxidation catalyst (m-509) and the catalyst used in industrial fluidized bed reactor of m-xylene to produce m-dicyanobenzene has been characterized by XPS, ICP. It is showed that a lot of carbon existed on the surface of the catalyst that had been used in industrial fluid bed reactor for six months. The main reason of the catalyst deactivation was the loss of the active components. The carbon existed on the surface of the used catalyst has little effecton the activity of the catalyst. |
| |
| Keywords: | deactivation of catalyst characterization of catalyst ammoxidation m-dicyanobenzene |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
