| 冰片基氯化镁与苯甲醛、对一硝基苯甲醛的还原反应 |
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| 引用本文： | 阮明德
,张永敏
,陈旭东
,黄磊.冰片基氯化镁与苯甲醛、对一硝基苯甲醛的还原反应[J].浙江大学学报(理学版),1986,13(1):66-68. |
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| 作者姓名： | 阮明德 张永敏 陈旭东 黄磊 |
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| 基金项目： | 中国科学院科学基金资助课题 |
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| 摘 要： | 本文研究了冰片基氯化镁与苯甲醛、对-硝基苯甲醛的还原反应。冰片基氯化镁与苯甲醛的反应得到苯甲醇和相应的氧化产物冰片烯以及还原缩合产物安息香;而与对-硝基苯甲醛的反应,则得到4,4`-二硝基安息香和冰片烯。
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| 关 键 词： | 冰片基氯化镁 苯甲醛的还原 安息香 |
Reduction of Benzaldehyde and p-Nitrobenzaldehyde by Bornyl Magnesium Chloride |
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| Ruan Mingde,Zhang Yongmin Chen Xudong,Huang Lei.Reduction of Benzaldehyde and p-Nitrobenzaldehyde by Bornyl Magnesium Chloride[J].Journal of Zhejiang University(Sciences Edition),1986,13(1):66-68. |
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| Authors: | Ruan Mingde Zhang Yongmin Chen Xudong Huang Lei |
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| Institution: | Ruan Mingde Zhang Yongmin Chen Xudong Huang Lei |
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| Abstract: | In this paper, the reactions of bornyl magnesium chloride with benzal-dehyde and p-nitrobenzaldehyde are studied. It is found that the reaction products of bornyl magnesium chloride with benzaldehyde are benzyl alcohol and its corresponding oxidation product, bornylenc, and reduction-condensation product, benzoin while the reaction products of this bornyl magnesium chloride with p-nitrobenzaldehyde are 4, 4'-dinitrobenzoin and bornylene. |
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| Keywords: | bornyl magnesium chloride reduction of benzaldehyde benzoin |
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