Preparation of organic/inorganic hybrid nanomaterials using aggregates of poly(stearyl methacrylate)-b-poly(3-(trimethoxysilyl) propyl methacrylate) as precursor |
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| Authors: | Junfeng Zhou Xiaochen Dong Qiang Yang Jianjun Wang Haojie Yu Xu Chen |
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| Institution: | State Key Laboratory of Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, People’s Republic of China |
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| Abstract: | A novel brush-type amphiphilic copolymer of PSMA-b-PTMSPMA was synthesized via ATRP technique. As-synthesized polymer was characterized by GPC and 1H NMR. It was of interest that the resultant polymer could self-assemble into micelles with different morphologies and sizes in selective solvents by adjusting the copolymer concentrations. These aggregates could be prepared into novel stable organic/inorganic hybrid nanomaterials by the gelation process. The size and structure of these aggregates and the corresponding hybrid nanomaterials were observed by TEM. |
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| Keywords: | Self-assembly Hybrid nanomaterials Block copolymer |
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