Preparation of POSS-based organic–inorganic hybrid mesoporous materials networks through Schiff base chemistry |
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Authors: | Yuancheng Qin Hongbo Ren Fanghua Zhu Lin Zhang Chengwei Shang Zhijun Wei Meiming Luo |
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Institution: | aKey Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, PR China;bResearch Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900, PR China |
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Abstract: | The synthesis of novel POSS-based organic–inorganic hybrid mesoporous materials networks functionalized with amine groups through Schiff base chemistry is reported. The material shows uniform mesoporous size. Nitrogen sorption analyses give high specific surface areas of 641–1103 m2 g−1 with pore volumes of 0.47–0.53 mL g−1. The combined results of FTIR, solid 13C NMR and 29Si NMR show that the POSS building blocks are successfully weaved in the porous structure without obvious alteration of the POSS structural characteristics. The hybrid materials show excellent thermal stability. |
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Keywords: | POSS Mesoporous materials High specific surface areas Schiff base chemistry |
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