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Facile synthesis of highly conductive polyaniline/graphite nanocomposites
Authors:XS Du  YZ Meng
Institution:a Institute of Energy and Environmental Materials, School of Physics and Engineering, Sun Yat-Sen University, 135 Xingang West, Guangzhou 510275, PR China
b Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, PR China
Abstract:A facile process for the synthesis of exfoliated graphite and polyaniline/graphite (PANI/graphite) nanocomposite was developed. Graphite nanosheets were prepared via the microwave irradiation and sonication from synthesized expandable graphite. The nanocomposites were fabricated via in situ polymerization of aniline monomer in the presence of graphite nanosheets. The nanoscale dispersion of graphite sheets was evidenced by the SEM and TEM examinations. According to the electrical conductivity test, the conductivity of the final PANI/graphite nanocomposites were dramatically increased compared with pristine PANI. From the thermogravimetric analysis, the introduction of graphite exhibits a beneficial effect on the thermal stability of PANI.
Keywords:Exfoliated graphite  X-ray diffraction  Nanocomposite  Conducting polymers
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