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Self-healing supramolecular gels formed by crown ether based host-guest interactions
Authors:Zhang Mingming  Xu Donghua  Yan Xuzhou  Chen Jianzhuang  Dong Shengyi  Zheng Bo  Huang Feihe
Institution:Department of Chemistry, Zhejiang University, Hangzhou, China.
Abstract:Automatic repair: a polymer with pendent dibenzo24]crown-8 units (purple in picture) was cross-linked by two bisammonium salts (green) to form two supramolecular gels based on host-guest interactions. These two gels are stimuli-responsive materials that respond to changes of the pH value and are also self-healing materials, as can be seen by eye and as evidenced by rheological data.
Keywords:gels  host–guest systems  molecular recognition  self‐assembly  self‐healing
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