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Phosphine‐Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds |
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| Authors: | Jonas H Muessig Melanie Thaler Rian D Dewhurst Valerie Paprocki Jens Seufert James D Mattock Alfredo Vargas Holger Braunschweig |
| Abstract: | The lability of B=B, B?P, and B–halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes undergo cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange. |
| Keywords: | 1 2-additions boron iodine low-valent main-group species multiple bonds |