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Reductive dehydroxylation of allyl alcohols by IspH protein |
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| Authors: | Gräwert Tobias Span Ingrid Bacher Adelbert Groll Michael |
| Institution: | Center for Integrated Protein Science, Lehrstuhl für Biochemie, Technische Universit?t München, Lichtenbergstrasse 4, 85747 Garching (Germany), Fax: (+49)?89‐289‐13363 |
| Abstract: | The biosynthesis of natural products is a treasure trove of unusual reaction mechanisms. This Minireview summarizes recent work on the structure and mechanism of IspH protein, which catalyzes the reductive dehydroxylation of an allyl alcohol in a biosynthetic pathway leading to isoprenoid precursors. |
| Keywords: | deoxyxylulose phosphate pathway iron–sulfur clusters isoprenoid biosynthesis IspH protein LytB protein |
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