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Carbon-Carbon Bond Formation from Carbon Monoxide and Hydride: The Role of Metal Formyl Intermediates**
Authors:Joseph M Parr  Prof?Dr Mark R Crimmin
Institution:Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, 82 Wood Lane, Shepherds Bush, London, W12 0BZ UK
Abstract:Current examples of carbon chain production from metal formyl intermediates with homogeneous metal complexes are described in this Minireview. Mechanistic aspects of these reactions as well as the challenges and opportunities in using this understanding to develop new reactions of CO and H2 are also discussed.
Keywords:Carbon Monoxide  Ethenediolate  Fischer Tropsch  Homologation  Metal Formyl
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