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Manufacturing metallic silver from its chalcogenides
Authors:O G Gromov  Yu A Savel’ev  G B Kunshina  E P Lokshin  S A Mastyugin  V T Kalinnikov
Institution:1616. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Apatity, Russia
2616. JSC “Uralelectromed,”, Verkhnyaya Pyshma, Russia
Abstract:The decomposition of silver selenide and sulfide to metallic silver and chalcogen containing oxygen compounds by sintering with an equimolar mixture of sodium nitrate and nitrite was examined. It was found that 100% recovery of silver in a metal phase is reached at 5% excess of sodium nitrate and nitrite and a time of the isothermal exposure at 375 °C 1 hour or half an hour at 400°C.
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