Kinetics of O(1D) interactions with the atmospheric gases N2, N2O,H2O,H2, CO2, and O3 |
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| Authors: | PH Wine AR Ravishankara |
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| Institution: | Molecular Sciences Group, Engineering Experiment Station, Georgia Institute of Technology, Atlanta, Georgia 30332, USA |
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| Abstract: | Rate coefficients for collisional removal of O(1D) by six atmospheric gases have been measured by monitoring the appearance of O(3P) following photolytic production of O(1D). The measured values, kM±2σ, in units of 10?11 cm?3 molecule ?1 s?1 are kO3 = 22.8±2.3, kN2 = 2.52 ± 0.25, kCO2 = 10.4 ± 1.0,kH2O 195± 2.0, kN2O = 11.7 ± 1.2, and kH2, = 11.8±1.2. |
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