Rate constants for the reaction of OH radicals with CH3CN, C2H5CN AND CH2=CH-CN in the temperature range 298–424 K |
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Authors: | G W Harris T E Kleindienst J N Pitts Jr |
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Institution: | Department of Chemistry and Statewide Air Pollution Research Center, University of California, Riverside, California 92521, USA |
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Abstract: | Rate constants for the reactions of OH with CH3CN, CH3CH2CN and CH2=CH-CN have been measured to be 5.86 × 10?13 exp(?1500 ± 250 cal mole?1/RT), 2.69 × 10?13 exp(?1590 ± 350 cal mole?1/RT and 4.04 × 10?12 cm3 molecule?1 s?1, respectively in the temperature range 298–424 K. These results are discussed in terms of the atmospheric lifetimes of nitrfles. |
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Keywords: | Address for correspondence: Chemistry Division Bhabha Atomic Research Centre Trombay Bombay-400 085 India |
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