Integral and state-to-state cross sections for the reaction D + H2(νf) → HD(νf) + H: A quantum mechanical study within the infinite order sudden approximation |
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Authors: | N Abusalbi DJ Kouri Y Shima M Baer |
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Institution: | Department of Chemistry and Department of Physics, University of Houston, Houston, Texas 77004, USA;Applied Mathematics, Soreq Nuclear Research Center, Yavne 70600, Israel |
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Abstract: | In this paper are presented quantum mechanical t-initial and t-average cross sections and rate constants for the reactions D + H2(ν1 = 0, 1) → HD(νf = 0, 1) + H. The calculations were done employing the infinite order sudden approximation. It was found that the t-average total cross sections overlap very nicely with the available classical cross sections. As for rate constants a reasonably good fit was found with available experimental results. |
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