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bis-alkylsulfonylpyridines
Authors:S G Woods  B T Matyas  A P Vinogradoff  Y C Tong
Institution:1. Western Applied Sciences and Technology Laboratories, Dow Chemical U.S.A., 2800 Mitchell Drive, Walnut Creek, California 94598

Brigham Young University, Provo, UT 84601.;2. Western Applied Sciences and Technology Laboratories, Dow Chemical U.S.A., 2800 Mitchell Drive, Walnut Creek, California 94598

Summer Student Trainee, 1979.;3. Western Applied Sciences and Technology Laboratories, Dow Chemical U.S.A., 2800 Mitchell Drive, Walnut Creek, California 94598

Abstract:Dihalogenated pyridines, some activated with carboxylic, ester or cyano group, were allowed to react with sodium alkylmercaptides. After hydrolysis of the ester or cyano group followed by decarboxylation, bis-alkylthiopyridines with substituents at 2,3-, 2,4-, 2,5-, 2,6- and 3,5-positions were prepared. These compounds were oxidized to bis-alkylsulfonylpyridines.
Keywords:
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