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Facile Synthesis of Novel Selenium‐Containing Benzopyrans
Authors:Zsolt Zsótér  Tibor Tímár  Krisztina Kónya  Tamás Patonay  József Jek?
Institution:1. Department of Organic Chemistry, University of Debrecen, Debrecen, Hungary;2. Ubichem Research Ltd., Budapest, Hungary;3. Department of Quality Control, SunPharma Ltd., Tiszavasvári, Hungary
Abstract:4,4‐Dimethylchromeno4,3‐d]selenadiazoles 8 with insecticide activities have been synthesized via oxidative ring closure of the corresponding semicarbazone derivatives 7 by treatment with selenium dioxide. Reaction of various alkoxy‐2,2‐dimethyl‐2H‐benzopyrans with phenylselenyl chloride was utilized to prepare different phenylselenyl‐ and 3‐chloro precocene analogs.
Keywords:
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