| 过氧化氢直接氧化苯制备苯酚的多相催化研究进展* |
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| 引用本文： | 包河彬,胡志德.过氧化氢直接氧化苯制备苯酚的多相催化研究进展*[J].化学教育,2021,42(4):8-16. |
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| 作者姓名： | 包河彬 胡志德 |
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| 作者单位： | 中国人民解放军陆军勤务学院基础部 重庆 401311 |
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| 基金项目： | 重庆市高等教育改革研究项目(183206);陆军勤务学院青年科研资助项目(LQ-QN-201812)。 |
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| 摘 要： | 作为一种绿色、洁净的氧化剂,使用过氧化氢直接氧化苯来制备苯酚的过程极具吸引力。综述了分子筛、碳基材料、金属氧化物、金属有机框架等多相催化剂在氧化苯制备苯酚反应中的应用,主要讨论了催化剂的合成路线、反应机理和催化性能,希望能为新的多相催化体系的合理设计提供有益的视角。
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| 关 键 词： | 过氧化氢 苯酚 多相催化 羟基化 光催化 石墨相氮化碳 分子筛 金属有机框架 |
Heterogeneous Catalysis for Direct Oxidation of Benzene to Phenol with Hydrogen Peroxide |
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| BAO He-Bin,HU Zhi-De.Heterogeneous Catalysis for Direct Oxidation of Benzene to Phenol with Hydrogen Peroxide[J].Journal of Chemical Education,2021,42(4):8-16. |
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| Authors: | BAO He-Bin HU Zhi-De |
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| Institution: | Fundamental Studies Department, Army Logistical University of PLA, Chongqing 401311, China |
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| Abstract: | As a green and clean oxidant,it is very attractive to oxidize benzene with hydrogen peroxide to obtain phenol.In this paper,different kinds of heterogeneous catalysts,such as molecular sieves,carbon-based materials,metal oxides and metal organic frameworks for the oxidation of benzene to phenol with hydrogen peroxide are reviewed.The preparation routes,reaction mechanisms and catalytic performances are mainly discussed.It can provide a useful perspective for rational design of new heterogeneous catalysis. |
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| Keywords: | hydrogen peroxide phenol heterogeneous catalysis hydroxylation photocatalysis g-C3N4 molecular sieve metal organic frameworks |
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