Tertiary Phosphine Oxides in Reaction with Benzaldehyde |
| |
| Authors: | Ivanova N I Gusarova N K Reutskaya A M Shaikhutdinova S I Arbuzova S N Trofimov B A |
| |
| Institution: | (1) Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, Russia |
| |
| Abstract: | Symmetrical and unsymmetrical tertiary phosphine oxides containing benzyl and 5-chloro-2-thienyl radicals stereoselectively react with benzaldehyde in the sodium amide-THF system to form the E isomers of 1-organyl-2-phenylethene and diorganylphosphinic acids in high yields. Triethyl, tris(2-phenyl- ethyl)-, and tris(4-methoxyphenyl)methyl]phosphine oxides under the above-mentioned conditions do not react with benzaldehyde. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
