Synthesis of Bis(tricarbonylcyclopentadienylmolybdenum)bismuth(III) Chloride and Its Reaction with Metals |
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| Authors: | Piskunov A V Maslennikov S V Spirina I V Artemov A N Malysheva E V |
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| Institution: | (1) Research Institute of Chemistry, Lobachevsky Nizhni Novgorod State University, Nizhni Novgorod, Russia |
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| Abstract: | Polynuclear organometallic compounds CpMo(CO)3]2BiCl and CpMo(CO)3]BiCl2 were prepared by reaction of bismuth with tricarbonylcyclopentadienylmolybdenum chloride in dimethyl sulfoxide (DMSO). CpMo(CO)3]2BiCl is reduced with magnesium or indium in tetrahydrofuran to give bismuth, CpMo(CO)3]3Bi, and magnesium or indium chloride. In the presence of DMSO, the reaction of CpMo(CO)3]2BiCl with magnesium or indium yields bismuth and the organomolybdenum derivative of magnesium or lithium, respectively. |
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