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Polymerization of organized polymer assemblies
Institution:1. Beijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;2. Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, Hubei Engineering Research Center for Biomaterials and Medical Protective Materials, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;3. Laboratoire de Chimie UMR 5182 / CNRS-ENS Lyon, Université Lyon 1, Ecole Normale Supérieure de Lyon, 46, allée d''Italie 69364, Lyon cedex 07, France;4. Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China;5. ZJU-Hangzhou Global Scientific and Technological Innovation Center, Hangzhou 311215, P. R. China;6. Green Catalysis Center and College of Chemistry, Zhengzhou University, Zhengzhou 450001, P. R. China;7. Department of Chemistry, 105 East 24th Street, Stop A5300, The University of Texas at Austin, Austin, Texas 78712-1224, United States
Abstract:Supramolecular chemistry has provided the means by which to selectively assemble small and large molecules into intricate two- and three-dimensional nanostructures. The past 2 years have witnessed considerable increase in extending such self-assembled structures into stable, single macromolecular nano-objects, through intra-assembly covalent bond formation. The selective polymerization of specific domains within organized polymer assemblies allows for the preparation of crosslinked, nanostructured bulk or particulate materials, with a variety of possible morphologies and properties.
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