Reaction of silicon tetrafluoride with calcium hydride as a propagating wave |
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Authors: | A D Bulanov V S Mikheev O Yu Troshin A Yu Lashkov |
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Institution: | (1) Institute of High-Purity Substances, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorod, 603600, Russia |
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Abstract: | The synthesis of silane by reacting silicon tetrafluoride and calcium hydride is shown to proceed as a propagating wave. The main parameters of the process, namely, the propagation velocity, the reaction front temperature, and calcium conversion, are determined. The mathematical model of wave propagation for an exothermic reaction in a porous medium with purging a gaseous oxidant describes qualitatively the major laws of the process. |
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