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New copper(II), nickel(II), and cobalt(II) chelates derived from 2-methyl-3-{[3-methyl-5-oxo-1-phenylpyrazol-4- ylidene)methyl]amino}-quinazolin-4-one
Authors:L D Popov  G I Bondarenko  S A Borodkin  Yu P Tupolova  V V Tkachev  G V Shilov  S I Levchenkov  I N Shcherbakov  E V Korshunova  E A Raspopova  V A Kogan
Abstract:Ligand system derived from pyrazolone-5 and N-aminoquinazolinone was prepared, its structure was studied. Metal chelates ML2 were prepared by reaction of the obtained ligand with copper(II), nickel(II), and cobalt(II) acetates. The complexes were studied by IR, electronic, and ESR spectroscopy, magnetochemistry, X-ray diffraction. Copper(II) complex was shown to have pseudo-tetrahedral structure, nickel(II) and cobalt(II) complexes are octahedral.
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