Backbone-thermoresponsive hyperbranched polyethers |
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Authors: | Jia Zhifeng Chen Hao Zhu Xinyuan Yan Deyue |
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Institution: | School of Chemistry and Chemical Technology, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, People's Republic of China. |
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Abstract: | A new type of materials, the backbone-thermoresponsive hyperbranched polyether, was successfully synthesized by proton-transfer polymerization of 1,4-butanediol diglycidyl ether and various triols, and the lower critical solution temperature (LCST) values can be readily adjusted from 19.0 to 40.3 degrees C by changing the hydrophilic/hydrophobic balance of BDE and triols. |
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