Coordination-driven self-assembly of supramolecular cages: heteroatom-containing and complementary trigonal prisms |
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Authors: | Kryschenko Yury K Seidel S Russell Muddiman David C Nepomuceno Angelito I Stang Peter J |
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Institution: | Department of Chemistry, University of Utah, 315 South 1400 East, Rm. 2020, Salt Lake City, Utah 84112, USA. |
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Abstract: | The self-assembly of three nanoscopic prisms of approximate size 1 x 4 nm is reported. Tetrahedral carbon, silicon, and phosphorus were used as structure-defining elements in these coordination-based cages. A carbon-based assembly completes a pair of nanoscopic complementary 3-D structures. The formation of the structures is supported by multinuclear NMR, ESI FT-ICR mass spectrometry, and elemental analysis data. |
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