Total synthesis of (-)-corilagin |
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| Authors: | Yamada Hidetoshi Nagao Kohei Dokei Kazutoyo Kasai Yusuke Michihata Naoki |
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| Institution: | School of Science and Technology, Kwansei Gakuin University, Sanda 669-1337, Japan. hidetosh@kwansei.ac.jp |
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| Abstract: | The synthesis of corilagin was achieved by the integration of the development of the oxidative coupling of the symmetrically protected gallates and the temporarily ring-opened synthetic route for the 3,6-hexahydroxydiphenoyl (HHDP) bridge. This is the first total synthesis of the 1C4/B-ellagitannins, which contain ring-flipped glucose. |
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