A conducting crystal based on a single-component paramagnetic molecule, [Cu(dmdt)(2)] (dmdt = dimethyltetrathiafulvalenedithiolate) |
| |
Authors: | Tanaka Hisashi Kobayashi Hayao Kobayashi Akiko |
| |
Institution: | Institute for Molecular Science, Myodaiji, Okazaki 444-8585, Japan. |
| |
Abstract: | A single-component conducting molecular crystal composed of paramagnetic copper complexes, Cu(dmdt)2]0+, was prepared. The crystal has an unprecedented three-dimensionally packed molecular arrangement and exhibits a fairly high conductivity (1 S cm-1 at room temperature). The magnetic susceptibility measurements revealed that Cu(dmdt)2]0+ molecule keeps most of S = 1/2 spin moments. The difference of the bond lengths between Cu(dmdt)2]0+ and Cu(dmdt)2]2- is consistent with the result of the molecular orbital calculation. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|