Acyclic telluroiminium salts: isolation and characterization |
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Authors: | Mutoh Yuichiro Murai Toshiaki Yamago Shigeru |
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Institution: | Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido, Gifu 501-1193, Japan. |
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Abstract: | The isolation, structure, and reactions of acyclic telluroiminium salts were disclosed. The delocalization of electrons on the tellurium atom and the partial double-bond character of C-Te bonds in the salts are discussed on the basis of X-ray molecular structure analysis, 13C and 125Te NMR spectroscopy, and molecular orbital calculation. |
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